- Spectrum splitting and enhanced light absorption in perovskite/Si tandem solar cells
- Microstructured optical coatings for radiative cooling of solar panels
- Nanopatterned optical coatings for coloured PV
- In-situ characterisation of perovskite thin film fabrication
- Light trapping in ultrahigh-efficiency III-V/Si tandem solar cells (with Fraunhofer ISE)
- Light trapping in thin Si solar cells
- Novel light management, LSC architectures
De Natuurkundige – Albert Polman Interview (in Dutch) NTvN 2020
Evolution of our PV research program
Plasmonic solar cells
In 2008, our group, together with the group of Harry Atwater at Caltech, started research on the use of nanophotonic concepts to enhance the efficiency and reduce the cost of photovoltaic energy conversion. Our initial paper Improved red response in thin-film a-Si solar cells with soft-imprinted plasmonic backreflectors was published in 2009. In 2010 we published a perspective/review paper on the many prospects of nanophotonic design for improved photovoltaics Plasmonics for improved photovoltaic devices (>6.000 citations), also highlighted as an Editorial article. This paper defined the research field of “Light management for photovoltaics” that took off in many labs worldwide. in 2012 together with Harry Atwater, we were awarded the ENI Renewable Energy Award for pioneering research on light management in photovoltaic materials.
Mie resonant light scattering, demonstrator devices, reviews & perspective articles
After our initial work on plasmonic solar cells we introduced dielectric Mie scatterers for resonant light coupling and trapping in solar cells. Our 2012 paper Omnidirectional antireflection coating based on subwavelength surface Mie resonators was the first to introduce this concept to improve solar cells. We wrote a perspective on Photonic design principles for ultrahigh-efficiency photovoltaics in Nature Materials (2012). We exploited our insights in plasmonic light scattering to create Transparent conducting silver nanowire networks. We expanded our research to create demonstrator devices and improved the efficiency of solar cells based on a wide range of materials: thin-film silicon, organic and CIGS solar cells, as well as silicon heterojunction solar cells. In another collaborative project with the group of Atwater at Caltech, we discovered Plasmoelectric potentials in metal nanostructures, published in Science in 2013. We promoted the use of Nanophotonics for shrinking light-based technology in a review in Science in 2016 and reviewed the state-of-the art in light management for PV in Photovoltaic materials – present efficiencies and future challenges in Science in 2017. We developed metagratings to create Combined Metagratings for Efficient broad angle scattering metasurface. In 2020 we published a Perspective article in ACS Photonics with all four AMOLF PV group leaders, presenting a wide range of opportunities for photonics for photovoltaics that appear based on all achievements so far. We developed spectrum splitters for 2-terminal and 4-terminal perovskite/silicon tandem solar cells based on resonant Mie gratings.
Novel concepts for large-area application, startups
While we developed fundamental insights developed, we started developing novel concepts that could help the introduction of nano-photovoltaics in practical applications. With Marc Verschuuren (Philips Research) we developed Large-area nanoimprint by substrate conformal imprint lithography (SCIL) to create nanopatterns on full-size solar cells. Marc, together with colleagues, has started a company, SCIL Nanomprint Solutions, that has brought the new technique on the market, with the first instruments sold to customers in 2017. In 2015 we developed a roadmap “Nanopatterning for Photovoltaics” together with ASML. Together with FEI/Thermo Fisher and Delmic we developed cathodoluminescence (CL) lifetime imaging as a novel technique to characterize photovoltaic nanomaterials. The new instrument was commercialized by Delmic, a start-up company co-founded by Albert Polman in 2012. Delmic now employs 40 people and has sold many CL instruments to customers allover the world. ThermoFisher sells the ultrafast beam blanker that we developed together to customers in semiconductor metrology. An independent analysis by Roland Berger shows that the sales of commercial products based on inventions and development in our group add 5 M€ to the Dutch economy every year.
Knowledge transfer
Technology transfer from academic research to real-world applications is one of the hardest things to do for a research group. It can take many years before an idea finds its way to the market and PV is no exception: the PERL technology that is now introduced in PV manufacturing was invented in the 1990s. To speed up knowledge transfer we have teamed up with the TNO Energy Transition (formerly ECN). Together with TNO we apply novel concepts developed in our group to solar cells that are made using industrial processes – where possible. Together with TNO/ECN we created Efficient colored silicon solar modules using integrated resonant dielectric nanoscatterers. This new concept won the SolarPower R&D Award at the EU-PVSEC conference in 2017. We developed Soft-imprinted Ag nanowire hybrid electrodes on industrial silicon heterojunction solar cells made by TNO/ECN. We participated in the COMPASS and RADAR programs that bring together academic and industrial research and technology development in the Netherlands. To facilitate knowledge transfer between our group and Wim Sinke (TNO) had a guest appointment at AMOLF. To further expand knowledge transfer opportunities, Albert Polman spent a sabbatical at the School of Photovoltaics and Renewable Energy Engineering at the University of New South Wales (Sydney), the institute that initiated much of present-day industrial Si PV technology. We appointed a joint PhD student that works at UNSW and AMOLF. We collaborate with the Fraunhofer Institute for Solar Energy Systems (Freiburg) on ultra-high efficiency III-V/Si tandem solar cells. We started a research program on roll-to-roll perovskite solar cells with HyET Solar, SparkNano, VDL, Delmic and Roland Berger. By setting up this broad network of collaborations with PV technology institutes we transfer relevant technology from our lab to applications in PV technology. Most recently, we co-initiated the national research, innovation and industrial development program SolarNL, to build up a new PV industry and Europe. It was awarded a subsidy of 312 M€ derma the National Growth Fund in 2023.
National PV research networks
To expand the effect of PV research we initiated several PV research programs in which other principal investigators within and outside AMOLF participated.
- 2008: FOM program Nanophotovoltaics (with AMOLF group leaders Polman, Bonn and Gomez Rivas, 2.1 M€, 6 researchers)
- 2012: FOM Focus group Light Management in new Photovoltaic Materials (LMPV, appointing three new group leaders Erik Garnett, Bruno Ehrler and Esther Alarcon Llado at AMOLF: 25 M€; 50 researchers)
- 2017: SOLARLab: Dutch national PV network, bringing together all 35 Principal Investigators at Dutch academic institutions, and TNO
- 2020: National Agenda Materials – Accelerating Materials Technologies
- 2021: National Growth Fund application Sustainable MaterialsNL (total M€ 640 subsidy awarded for circular plastics, batteries and sustainable steel)
- 2023: National Growth Fund application SolarNL: Circular integrated high-efficiency solar panels (312 M€ subsidy awarded, total program 898 M€)
With these national initiatives we maximize the impact of academic research and optimize knowledge transfer to industrial applications.
Outreach
We have developed a Theatre lecture performance “Voor niets gaat de zon op – “The sun rises for free”, to promote photovoltaics to the general public.
Our publications on nano-photovoltaics
: joint papers with TNO Energy Transition (former ECN); joint papers with Philips/SCIL nanoimprint solutions
2023
- Wafer-bonded two-terminal III-V//Si triple-junction solar cell with power conversion efficiency of 36.1 % at AM1.5g
P. Schygulla, R. Müller, O. Höhn, M. Schachtner, D. Chojniak, A. Cordaro, S. Tabernig, B. Bläsi, A. Polman, G. Siefer, D. Lackner, and F. Dimroth, Progr. Photovolt. 32, 1-9 (2023) - Nano-patterned back-reflector with engineered near-field/far-field light scattering for enhanced light trapping in silicon-based multi-junction solar cells
A. Cordaro, R. Müller, S. Tabernig, N. Tucher, P. Schygulla, O. Höhn, B. Bläsi, and A. Polman, ACS Photon. 10, 4061 (2023) - Carrier generation and collection in Zn3P2/InP heterojunction solar cells
R. Paul, S.W. Tabernig, J.R. Sapera, J. Hurni, A. Tiede, X. Liu, D.A. Damry, V. Conti, M. Zamani, S. Escobar Steinvall, M. Dimitrievska, E. Alarcon Lladó, V. Piazza, J. Boland, F.-J. Haug, A.Polman, and A. Fontcuberta i Morral, Solar En. Mater. Solar Cells 256, 112349 (2023)
Nanopatterned SiNx broadband antireflection coating for planar silicon solar cells
A. Cordaro*, S.W. Tabernig*, M. Pollard, C. Yi, E. Alarcon-Llado, B. Hoex, and A. Polman, Phys. Stat. Sol. A. 2200827 (2023)
2022
- Passive radiative cooling of silicon solar modules with photonic silica microcylinders
E. Akerboom, T. veeken, C. Hecker, J. van de Groep, and A. Polman, ACS. Photon. 9, 3831 (2022) - Beyond light trapping benefits – the effect of SiO2 nanoparticles in bifacial transparent ultrathin Cu(In, Ga)Se2 solar cells
Y. Li, S.W. Tabernig, G. Yin, A. Polman, and M. Schmid, Solar RRL 2200695 (2022) - Optically resonant bulk heterojunction PbS quantum dot solar cell
W. Tabernig, L. Yuan, A. Cordaro, Z.L. Teh, Y. Gao, R. Patterson, A. Pusch, S. Huang, and A. Polman, ACS Nano, DOI:10.1021/acsnano.1c11330 (2022) - Nanopatterning of perovskite thin films for enhanced and directional light emission
L.A. Muscarella, A. Cordaro, G. Krause, D. Pal, G. Grimaldi, D. Langhorst, A. Callies, B. Bläsi, O. Höhn, F.A. Koenderink, A. Polman, and B. Ehrler, ACS Mater. Interf. doi.org/10.1021/acsami.2c09643 (2022) - Avoiding shading losses in concentrator photovoltaics using a soft-imprinted cloaking geometry
S.W. Tabernig, A.H. Soeriyadi, U. Römer, A. Pusch, D. Lamers, M.P. Nielsen, A. Polman, N.J. Ekins-Daukes, IEEE J. Photovolt. 10.1109/JPHOTOV.2022.3182277 (2022) - Plasma focused ion beam tomography for accurate characterization of black silicon validated by full wave optical simulation
Y. Zhang T. Veeken, S. Wang, G. Scardera, M. Abbott, D. Payne, A. Polman, and B. Hoex, ACS Appl. Mater. Interf. 2200068 (2022) - Detailed-balance efficiency limits of two-terminal perovskite/silicon tandem solar cells with planar and Lembertian spectral splitters
V. Neder, S.W. Tabernig, and A. Polman, J. Photon. Energy. 12, 15502 (2022) - Directional quantum dot emission by soft-stamping on silicon Mie resonators
T. Veeken, B. Daiber, H. Agrawal, M. Aarts, E. Alarcón-Lladó, E.C. Garnett, B. Ehrler, J. van de Groep and A. Polman, Nanoscale Adv. 4, 1088 (2022)
2021
- Unlocking higher power efficiencies in luminescent solar concentrators through anisotropic luminophore emission
J.S. van der Burgt, D.R. Needell, T. Veeken, A. Polman, E.C. Garnett, and H.A. Atwater, ACS Appl. Mater. Interf. 13, 40742 (2021) - Broadband angular color stability of dielectric thin film-coated pyramidal textured Si for photovoltaics
N. Roosloot, V. Neder, H. Haug, C.C. You, A. Polman, and E.S. Marstein, J. Appl. Phys. 129, 173104 (2021) - Photonics for photovoltaics- Advances and opportunities
E.C. Garnett, B. Ehrler, A. Polman, and E. Alarcon Llado, ACS Photon. 8, 61 (2021)
2020
- Four-terminal perovskite/Si tandem solar cell with integrated Mie-resonant spectrum splitter metagrating
Neder, D. Zhang, S. Veenstra, and A. Polman, ArXiv.2012.12649 (2020) - Detailed-balance efficiency limits of two-terminal perovskite/silicon tandem solar cells with planar and Lambertian spectral splitters
V. Neder, S.W. Tabernig, and A. Polman, ArXiv.2012.12636 (2020) - Photovoltaics reaching for the Shockley-Queisser limit
B. Ehrler, E. Alarcon Llado, S.W. Taberni, T. Veeken, E. Garnett, and A. Polman, ACS Energy Lett. 5, 3029 (2020) - Resonant metagratings for spectral and angular control of light for colored rooftop photovoltaics
F. Uleman, V. Neder, A. Cordaro and A. Polman, ACS Applied Energy Mater. 3, 3150 (2020)
2019
- Application and validity of the effective medium approximation to the optical properties of nanotextured silicon coated with a dielectric layer
T. Fung, T.P.N. Veeken, D. Payne, B. Vettil, A. Polman, and M. Abbott, Optics Express 27, 38645 (2019) - Tunable plasmonic HfN nanoparticles and arrays
S. Askes, N. Schilder, A. Polman, and E. Garnett, Nanoscale 11, 20252 (2019) - Electron-beam spectroscopy for nanophotonics
A. Polman, M. Kociak, and J. Gavier de Abajo, Nature Mater. 18, 1158 (2019) - Nanoscale spatial limitations of large-area substrate-conformal imprint lithography
A. Verschuuren, M.W. Knight, M. Megens, and A. Polman, Nanotechnology 30, 345301 (2019) - Combined metagratings for efficient broad-angle scattering metasurface
V. Neder, Y. Ra’di, A. Alu, and A. Polman, ACS Photon. 6, 1010 (2019)
2018
- Complementary cathodoluminescence lifetime imaging configurations in a scanning electron microscope
S. Meuret, M. Solà Garcia, T. Coenen, E. Kieft, H. Zeijlemaker, M. Lätzel, S. Christiansen, S.Y. Woo, Y.H. Ra, Z. Mi, and A. Polman, Ultramicroscopy 197, 28 (2019) - Shape-preserving transformation of carbonate minerals into lead halide perovskite semiconductors based on ion exchange/insertion reactions
T. Holtus, L. Helmbrecht, H.C. Hendrikse, I. Baglai, S. Meuret, G.W.P. Adhyaksa, E. C. Garnett and W.L. Noorduin, Nature Chem. 10, 740 (2018) - Efficient green emission from wurtzite AlxIn1xP nanowires
L. Gagliano, M. Kruijsse, J.D.D. Schefold, A. Belabbes, M.A. Verheijen, S. Meuret, S. Koelling, A. Polman, F. Bechstedt, J.E.M. Haverkort, and E.P.A.M. Bakkers, Nano Lett. 18, 3543 (2018) - Nanoscale relative emission efficiency mapping using CL g(2) imaging
S. Meuret, T. Coenen, S. Woo, Y.-H. Ra, Z. Mi and A. Polman, Nano Lett. 18, 2288 (2018)
2017
- Efficient colored silicon solar modules using integrated resonant dielectric nanoscatterers
V. Neder, S.L. Luxembourg, and A. Polman, Appl. Phys. Lett. 111, 073902 (2017) - Colored solar modules using integrated pixelated resonant dielectric nanoscatterer arrays
V. Neder, S.L. Luxembourg, and A. Polman, Proc. EU-PVSEC Conference (2017), p. 34, doi:10.4229/EUPVSEC2017-1AO.3.5 - Large-area nanoimprint by substrate conformal imprint lithography (SCIL)
M.A. Verschuuren, M. Megens, J.F. Ni, H. van Sprang and A. Polman, Adv. Opt. Tech. 6, 243 (2017) - Light trapping in crystalline silicon thin film solar cells by nanostructured optical coatings
P. Spinelli, B.K. Newman, and A. Polman, in: “Nanotechnology for Energy Sustainability”, B. Raj, M. van de Voorde, Y. Mahajan (Eds.), Wiley, ISBN: 978-3-527-34014-9 (2017), p. 163 - Monocrystalline nanopatterns made by nanocube assembly and epitaxy
B. Sciacca, A. Berkhout, B.J.M. Brenny, S. Oener, M.A. van Huis, A. Polman, and E.C. Garnett, Adv. Mater. 29, 1701064 (2017) - Opto-electronic enhancement of ultrathin CIGS solar cells
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2016
- Soft-imprinted Ag nanowire hybrid electrodes on silicon heterojunction solar cells
M.W. Knight, J. van de Groep, P. Bronsveld, W.C. Sinke, and A. Polman, Nano Energy 30, 398 (2016) - Photovoltaic materials – present efficiencies and future challenges
A. Polman, M.W. Knight, E.C. Garnett, B. Ehrler, and W.C. Sinke, Science 352, 307 (2016) with supplemental - Metal−insulator−semiconductor nanowire network solar cells
S.Z. Oener, J. van de Groep, B. Macco, P.C.P. Bronsveld, W.M.M. Kessels, A. Polman, and E.C. Garnett, Nano Lett. 16, 3689 (2016) - Plasmonic scattering back reflector for light trapping in flat nanocrystalline silicon solar cells
L. van Dijk, J. van de Groep, L.W. Veldhuizen, M. di Vece, A. Polman, and R.E.I. Schropp, ACS Photon. 3, 685 (2016) - Thermodynamic theory of the plasmo-electric effect
J. van de Groep, M. Sheldon, H.A. Atwater, and A. Polman, Sci. Rep. 6, 23283 (2016) - Direct imaging of hybridized eigenmodes in coupled silicon nanoparticles
J. van de Groep, T. Coenen, S.A. Mann, and A. Polman, Optica 3, 93 (2016) - Solution-grown silver nanowire ordered arrays as transparent electrodes
B. Sciacca, J. van de Groep, A. Polman and E.C. Garnett, Adv. Mater. 28, 905 (2016)
2015
- Efficient nanorod-based amorphous silicon solar cells with advanced light trapping
Y. Kuang, M.C. van Lare, A. Polman, L.W. Veldhuizen, J.K. Rath and R.E.I. Schropp, J. Appl. Phys. 118, 185307 (2015) - Light coupling and trapping in ultra-thin Cu(Ga,In)Se2 solar cells using dielectric scattering patterns
M.C. van Lare, G. Yin, A. Polman, and M. Schmid, ACS Nano 9, 9603 (2015) - Dielectric scattering patterns for efficient light trapping in thin-film solar cells
M.C. van Lare, F. Lenzmann, and A. Polman, Nano Lett. 15, 4846 (2015) - Optimized scattering power spectral density of photovoltaic light trapping patterns
M.C. van Lare and A. Polman, ACS Photon. 2, 822 (2015) - Single-step soft-imprinted large-area nanopatterned anti-reflection coating
J. van de Groep, P. Spinelli, and A. Polman, Nano Lett. 15, 4223 (2015) - Large-area soft-imprinted nanowire networks as light trapping transparent conductors
J. van de Groep, D. Gupta, M.A. Verschuuren, M.M. Wienk, R.A.J. Janssen, and A. Polman, Sci. Rep. 5, 11414 (2015) - Nanophotonics: shrinking light-based technology
A.F. Koenderink, A. Alù, and A. Polman, Science 348, 516 (2015) - Effect of EVA encapsulation on light trapping in thin-film c-Si solar cells by using plasmonic and Mie nanoscatterers
P. Spinelli, F. Lenzmann, A. Weeber, A. Polman, IEEE J. Photovolt. 5, 559 (2015) - Limiting light escape angle in silicon photovoltaics: ideal and realistic cells
E.D. Kosten, B.K. Newman, A. Polman and H.A. Atwater, IEEE J. Photovolt. 5, 61 (2015)
2014
- Plasmoelectric potentials in metal nanostructures
M.T. Sheldon, J. van de Groep, A.M. Brown, A. Polman and H.A. Atwater, Science 346, 828 (2014) - Limiting light escape angle in silicon photovoltaics: ideal and realistic cells
E.D. Kosten, B.K. Newman, A. Polman and H.A. Atwater, IEEE J. Photovolt. 5, 61 (2015) - Light trapping in thin crystalline Si solar cells using surface Mie scatterers
P. Spinelli and A. Polman, IEEE J. Photovolt. 4, 554 (2014)
2013
- Designing dielectric resonators on substrates: Combining magnetic and electric resonances
J. van de Groep and A. Polman, Optics Express 21, 26285 (2013); highlighted by OSA - Dielectric back scattering patterns for light trapping in thin-film Si solar cells
M.C. van Lare, F. Lenzmann, and A. Polman, Optics Express 21, 20738 (2013) - Al2O3/TiO2 nano-pattern antireflection coating with ultralow surface recombination
P. Spinelli, B. Macco, M. A. Verschuuren, W.M.M. Kessels, and A. Polman, Appl. Phys. Lett. 102, 233902 (2013) - Plasmonic light-trapping in a-Si:H solar cells by front-side Ag nanoparticle arrays: A benchmarking study
F.O. Lenzmann, M.C. van Lare, J. Salpakari, P. Spinelli, J.B. Notta, M. Dörenkämper, N.J. Bakker, A.W. Weeber, and A. Polman, Phys. Stat. Sol. A 210, 1571 (2013) - Solar steam nanobubbles
A. Polman, ACS Nano 7, 15 (2013) - Highly efficient GaAs solar cells by limiting light emission angle
E.D. Kosten, J.H. Atwater, J. Parsons, A. Polman and H.A. Atwater, Light, Science and Appl. 2, e45 (2013)
2012
- Mode coupling by plasmonic surface scatterers in thin-film silicon solar cells
M. van Lare, F. Lenzmann, M.A. Verschuuren, and A. Polman, Appl. Phys. Lett. 101, 221110 (2012) - Photonic design principles for ultrahigh-efficiency photovoltaics
A. Polman and H.A. Atwater, Nature Mater. 11, 174 (2012) - Prospects of near-field plasmonic absorption enhancement in semiconductor materials using embedded Ag nanoparticles
P. Spinelli and A. Polman, Optics Express 20, 641 (2012) - Broadband omnidirectional antireflection coating based on subwavelength surface Mie resonators
P. Spinelli, M.A. Verschuuren, and A. Polman, Nature Comm. 3, 692 (2012) - Transparent conducting silver nanowire networks
J. van de Groep, P. Spinelli, and A. Polman, Nano Lett. 12, 3138 (2012) - Plasmonic light trapping in thin-film solar cell nanostructures
P. Spinelli, V.E. Ferry, C. van Lare, J. van de Groep, M.A. Verschuuren, R.E.I. Schropp, H.A. Atwater, and A. Polman, Journ. Opt. 14, 24002 (2012)
2011
- Modeling light trapping in nanostructured solar cells
V.E. Ferry, A. Polman and H.A. Atwater, ACS Nano 5, 10055 (2011) - Optimized spatial correlations for broadband light trapping in ultra-thin a-Si:H solar cells
V.E. Ferry, M.A. Verschuuren, C. van Lare, R.J. Walters, R.E.I. Schropp, H.A. Atwater, and A. Polman, Nano Lett. 11, 4239 (2011) - Microphotonic parabolic light directors fabricated by two-photon lithography
J.H. Atwater, P. Spinelli, E. Kosten, J. Parsons, C. Van Lare, J. van de Groep, J. Garcia de Abajo, A. Polman, and H.A. Atwater, Appl. Phys. Lett. 99, 151113 (2011) - Controlling Fano lineshapes in plasmon-mediated light coupling into a substrate
P. Spinelli, C. van Lare, E. Verhagen and A. Polman, Optics Express 19, A303 (2011) - Resonant SPP modes supported by discrete metal nanoparticles on high-index substrate
F.J. Beck, E. Verhagen, S. Mokkapati, A. Polman, and K.R. Catchpole. Optics Express 19, A146 (2011) - Resonant nano-antennas for light trapping in plasmonic solar cells
S. Mokkapati, F.J. Beck, R. de Waele, A. Polman and K. R. Catchpole, J. Phys. D: Appl. Phys. 44, 185101 (2011) - Optical impedance matching using coupled metal nanoparticle arrays
P. Spinelli, M. Hebbink, R. de Waele, L. Black, F. Lenzmann and A. Polman, Nano Lett. 11, 1760 (2011)
2010
- Light trapping in ultrathin plasmonic solar cells
V.E. Ferry, M.A. Verschuuren, H.B.T. Li, E. Verhagen, R.J. Walters, R.E.I. Schropp, H.A. Atwater, and A. Polman, Optics Express 18, A237 (2010) - Asymmetry in photocurrent enhancement by plasmonic nanoparticle arrays located on the front or on the rear of solar cells
F.J. Beck, S. Mokkapati, A. Polman, and K. R. Catchpole, Appl. Phys. Lett. 96, 033113 (2010) - Plasmonics for improved photovoltaic devices
H.A. Atwater and A. Polman, Nature Materials 9, 205 (2010) and Editorial article
2009
2008
- Plasmonics applied
A. Polman, Science 322, 868 (2008) - Design principles for particle plasmon enhanced solar cells
K.R. Catchpole and A. Polman, Appl. Phys. Lett. 93, 191113 (2008) - Plasmonic solar cells
K.R. Catchpole and A. Polman, Optics Express 16, 21793 (2008)